| No. | Name | Title | Tenure |
|---|---|---|---|
| 1 | Daniel L. Mfinanga | High Commissioner | 1962 – 1965 |
| 2 | Salim A. Salim | High Commissioner | 1965 – 1968 |
| 3 | Sebastian Chale | High Commissioner | 1968 – 1971 |
| 4 | Ahmed H. Diria | High Commissioner | 1971 – 1978 |
| 5 | George M. Nhigula | High Commissioner | 1978 – 1980 |
| 6 | Mohamed A. Foum | High Commissioner | 1980 – 1984 |
| 7 | Mohamed R. Abdiwawa | High Commissioner | 1984 – 1989 |
| 8 | Onesiphorus H. Tesha | High Commissioner | 1989 – 1991 |
| 9 | Gertrude I. Mongella | High Commissioner | 1992 – 1993 |
| 10 | Alfred C. Tandau | High Commissioner | 1993 – 1995 |
| 11 | Ahmed Kiwanuka | High Commissioner | 1996 - 2002 |
| 12 | Eva L. Nzaro | High Commissioner | 2002 - 2007 |
| 13 | John W.H. Kijazi | High Commissioner | 2007- 2016 |
| 14 | Baraka H. Luvanda | High Commissioner | May, 2017 - September, 2021 |
